We have a new paper out in Org. Lett.! Isuru, Frank, Georgia, and Lasith show that diphenic acid derivatives undergo transient geometry changes on treatment with carbodiimide fuels.
Group News
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New paper in Org. Lett.
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New paper in Eur. J. Org. Chem.
A new paper is out in Eur. J. Org. Chem.! Viraj and our collaborators Briana Schrage and Chris Ziegler from the University of Akron study the assembly of hydrocarbon o-phenylene macrocycles assembled using olefin metathesis. We continue to learn more and more about assembling foldamers into more complex structures, and the molecules are particularly pretty.
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New paper in Angew. Chem.
We have a new paper out in Angew. Chem.! Mosharraf and Josh show that carbodiimide-fueled anhydride formation can be used to assemble macrocycles containing multiple transient bonds. We believe this will have significant implications for generating out-of-equilibrium species of increased structural complexity.
Many thanks to the editors for selecting this as a “Hot Paper”!
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New paper in J. Org. Chem.
Our latest paper is out in J. Org. Chem.! Lasith, Run, and our collaborators from the Sommer Group investigate structure–property effects in the assembly/disassembly of aqueous benzoic anhydrides fueled by carbodiimides.
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Renuka Baral, Andrew Miller, and Nadeen Saleh join group
Welcome to new graduate students Renuka Baral and Andrew Miller and new undergraduate Nadeen Saleh!
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Will Carson and Griffin Betz join group
Welcome to Will Carson and Griffin Betz, who have joined the group as undergraduate researchers!
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Meng Gu, Sean Ginn, Kiley Blachaniec, and Kaitlyn Flynn join group
Welcome to undergraduates Meng Gu, Sean Ginn, Kiley Blachaniec, and Kaitlyn Flynn, who have joined the group!
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New paper in Chem. Sci.
Our latest paper is out in Chemical Science! Zach and Viraj explore the interplay between folding and macrocyclization with ortho-phenylene hexamers and decamers. Confinement within the macrocycle forces the foldamer into conformations that are typically not observed, which is predictable using simple computational models.