Triphenylene-fused porphyrins

Lin Jiang, James T. Engle, Laura Sirk, C. Scott Hartley, Christopher J. Ziegler, and Hong Wang*
Org. Lett. 2011, 13, 3020–3023
[Published version]


Triphenylene has been successfully fused to the porphyrin periphery through a convenient oxidative ring-closure reaction. Bistriphenylene-fused porphyrins and a dibenzo[fg,op]tetracene-fused porphyrin have also been obtained using a similar approach. These π-extended porphyrins exhibited broadened and bathochromic shifted UV–vis absorptions.